Claimed detection of PH3 in the clouds of Venus is Consistent with Mesospheric SO2 (The Astrophysical Journal, 2021)

The observation of a 266.94 GHz feature in the Venus spectrum has been attributed to phosphine (PH3) in the Venus clouds, suggesting unexpected geological, chemical, or even biological processes. Since both PH3 and sulfur dioxide (SO2) are spectrally active near 266.94 GHz, the contribution to this line from SO2 must be determined before it can be attributed, in whole or part, to PH3. An undetected SO2 reference line, interpreted as an unexpectedly low SO2 abundance, suggested that the 266.94 GHz feature could be attributed primarily to PH3. However, the low SO2 and the inference that PH3 was in the cloud deck posed an apparent contradiction. Here we use a radiative transfer model to analyze the PH3 discovery, and explore the detectability of different vertical distributions of PH3 and SO2. We find that the 266.94 GHz line does not originate in the clouds, but above 80 km in the Venus mesosphere. This level of line formation is inconsistent with chemical modeling that assumes generation of PH3 in the Venus clouds. Given the extremely short chemical lifetime of PH3 in the Venus mesosphere, an implausibly high source flux would be needed to maintain the observed value of 20 ± 10 ppb. We find that typical Venus SO2 vertical distributions and abundances fit the JCMT 266.94 GHz feature, and the resulting SO2 reference line at 267.54 GHz would have remained undetectable in the ALMA data due to line dilution. We conclude that nominal mesospheric SO2 is a more plausible explanation for the JCMT and ALMA data than PH3.

Continue Reading →

Complications in the ALMA Detection of Phosphine at Venus (The Astrophysical Journal, 2021)

Recently published Atacama Large Millimeter Array (ALMA) observations suggest the presence of 20 ppb PH3 in the upper clouds of Venus. This is an unexpected result, as PH3 does not have a readily apparent source and should be rapidly photochemically destroyed according to our current understanding of Venus atmospheric chemistry. While the reported PH3 spectral line at 266.94 GHz is nearly colocated with an SO2 spectral line, the nondetection of stronger SO2 lines in the wideband ALMA data is used to rule out SO2 as the origin of the feature. We present a reassessment of wideband and narrowband data sets derived from these ALMA observations. The ALMA observations are re-reduced following both the initial and revised calibration procedures discussed by the authors of the original study. We also investigate the phenomenon of apparent spectral line dilution over varying spatial scales resulting from the ALMA antenna configuration. A 266.94 GHz spectral feature is apparent in the narrowband data using the initial calibration procedures, but this same feature cannot be identified following calibration revisions. The feature is also not reproduced in the wideband data. While the SO2 spectral line is not observed at 257.54 GHz in the ALMA wideband data, our dilution simulations suggest that SO2 abundances greater than the previously suggested 10 ppb limit would also not be detected by ALMA. Additional millimeter, submillimeter, and infrared observations of Venus should be undertaken to further investigate the possibility of PH3 in the Venus atmosphere.

Continue Reading →

The Habitability of Proxima Centauri b: Environmental States and Observational Discriminants (Astrobiology, 2018)

Proxima Centauri b provides an unprecedented opportunity to understand the evolution and nature of terrestrial planets orbiting M dwarfs. Although Proxima Cen b orbits within its star’s habitable zone, multiple plausible evolutionary paths could have generated different environments that may or may not be habitable. Here, we use 1-D coupled climate-photochemical models to generate self-consistent atmospheres for several evolutionary scenarios, including high-O2, high-CO2, and more Earth-like atmospheres, with both oxic and anoxic compositions. We show that these modeled environments can be habitable or uninhabitable at Proxima Cen b’s position in the habitable zone. We use radiative transfer models to generate synthetic spectra and thermal phase curves for these simulated environments, and use instrument models to explore our ability to discriminate between possible planetary states.

Continue Reading →

The inner edge of the habitable zone for synchronously rotating planets around low-mass stars using general circulation models (The Astrophysical Journal, 2016)

Terrestrial planets at the inner edge of the habitable zone (HZ) of late-K and M-dwarf stars are expected to be in synchronous rotation, as a consequence of strong tidal interactions with their host stars. Previous global climate model (GCM) studies have shown that, for slowly rotating planets, strong convection at the substellar point can create optically thick water clouds, increasing the planetary albedo, and thus stabilizing the climate against a thermal runaway. However these studies did not use self-consistent orbital/rotational periods for synchronously rotating planets placed at different distances from the host star. Here we provide new estimates of the inner edge of the HZ for synchronously rotating terrestrial planets around late-K and M-dwarf stars using a 3D Earth-analog GCM with self-consistent relationships between stellar metallicity, stellar effective temperature, and the planetary orbital/rotational period.

Continue Reading →

Water vapour absorption in the clear atmosphere of a Neptune-sized exoplanet (Nature, 2014)

Here we report observations of the transmission spectrum of the exoplanet HAT-P-11b (which has a radius about four times that of Earth) from the optical wavelength range to the infrared. We detected water vapour absorption at a wavelength of 1.4 micrometres. The amplitude of the water absorption (approximately 250 parts per million) indicates that the planetary atmosphere is predominantly clear down to an altitude corresponding to about 1 millibar, and sufficiently rich in hydrogen to have a large scale height (over which the atmospheric pressure varies by a factor of e).

Continue Reading →

Warming early Mars with CO2 and H2 (Nature Geoscience, 2013)

The presence of valleys on ancient terrains of Mars suggests that liquid water flowed on the martian surface 3.8 Gyr ago or before. The above-freezing temperatures required to explain valley formation could have been transient, in response to the frequent large meteorite impacts on early Mars, or they could have been caused by long-lived greenhouse warming. Climate models that consider only the greenhouse gases carbon dioxide and water have been unable to recreate warm surface conditions, given the lower solar luminosity at that time. Here we use a one-dimensional climate model to demonstrate that an atmosphere containing 1.3–4 bar of CO2 and water, in addition to 5–20% H2, could have raised the mean surface temperature of early Mars above the freezing point of water. Vigorous volcanic outgassing from a highly reduced early martian mantle is expected to provide sufficient atmospheric H2 and CO2—the latter from the photochemical oxidation of outgassed CH4 and CO—to form a CO2 and H2 greenhouse. Such a dense early martian atmosphere is consistent with independent estimates of surface pressure based on cratering data.

Continue Reading →

A dynamically-packed planetary system around GJ 667C with three super-Earths in its habitable zone (Astronomy & Astrophysics, 2013)

Doppler measurements of GJ 667C are described better by six (even seven) Keplerian-like signals: the two known candidates
(b and c); three additional few-Earth mass candidates with periods of 92, 62 and 39 days (d, e and f); a cold super-Earth in a 260-day
orbit (g) and tantalizing evidence of a ∼ 1 M⊕ object in a close-in orbit of 17 days (h). We explore whether long-term stable orbits are
compatible with the data by integrating 8×104
solutions derived from the Bayesian samplings. We assess their stability using secular
frequency analysis.

Continue Reading →

Infrared Transmission Spectroscopy of the Exoplanets HD209458b and XO-1b Using the Wide Field Camera-3 on the Hubble Space Telescope (The Astrophysical Journal, 2013)

We here report WFC3 spectroscopy of the giant planets HD209458b and XO-1b in transit, using spatial scanning mode for maximum photon-collecting efficiency. We introduce an analysis technique that derives the exoplanetary transmission spectrum without the necessity of explicitly decorrelating instrumental effects, and achieves nearly photon-limited precision even at the high flux levels collected in spatial scan mode. Our errors are within 6-percent (XO-1) and 26-percent (HD209458b) of the photon-limit at a spectral resolving power of 70, and are better than 0.01-percent per spectral channel.

Continue Reading →

A Revised Estimate of the Occurrence Rate of Terrestrial Planets in the Habitable Zones around Kepler M-dwarfs (ApJ Letters, 2013)

Because of their large numbers, low-mass stars may be the most abundant planet hosts in our Galaxy. Furthermore, terrestrial planets in the habitable zones (HZs) around M-dwarfs can potentially be characterized in the near future and hence may be the first such planets to be studied. Recently, Dressing & Charbonneau used Kepler data and calculated the frequency of terrestrial planets in the HZ of cool stars to be $0.15^{+0.13}_{-0.06}$ per star for Earth-size planets (0.5-1.4 R ⊕). However, this estimate was derived using the Kasting et al. HZ limits, which were not valid for stars with effective temperatures lower than 3700 K. Here we update their result using new HZ limits from Kopparapu et al. for stars with effective temperatures between 2600 K and 7200 K, which includes the cool M stars in the Kepler target list.

Continue Reading →

Habitable Zones around Main-sequence Stars: New Estimates (The Astrophysical Journal, 2013)

Identifying terrestrial planets in the habitable zones (HZs) of other stars is one of the primary goals of ongoing radial velocity (RV) and transit exoplanet surveys and proposed future space missions. Most current estimates of the boundaries of the HZ are based on one-dimensional (1D), cloud-free, climate model calculations by Kasting et al. However, this model used band models that were based on older HITRAN and HITEMP line-by-line databases. The inner edge of the HZ in the Kasting et al. model was determined by loss of water, and the outer edge was determined by the maximum greenhouse provided by a CO2 atmosphere. A conservative estimate for the width of the HZ from this model in our solar system is 0.95-1.67 AU. Here an updated 1D radiative-convective, cloud-free climate model is used to obtain new estimates for HZ widths around F, G, K, and M stars. New H2O and CO2 absorption coefficients, derived from the HITRAN 2008 and HITEMP 2010 line-by-line databases, are important improvements to the climate model. According to the new model, the water-loss (inner HZ) and maximum greenhouse (outer HZ) limits for our solar system are at 0.99 and 1.70 AU, respectively, suggesting that the present Earth lies near the inner edge. Additional calculations are performed for stars with effective temperatures between 2600 and 7200 K, and the results are presented in parametric form, making them easy to apply to actual stars. The new model indicates that, near the inner edge of the HZ, there is no clear distinction between runaway greenhouse and water-loss limits for stars with T eff lesssim 5000 K, which has implications for ongoing planet searches around K and M stars. To assess the potential habitability of extrasolar terrestrial planets, we propose using stellar flux incident on a planet rather than equilibrium temperature. This removes the dependence on planetary (Bond) albedo, which varies depending on the host star’s spectral type. We suggest that conservative estimates of the HZ (water-loss and maximum greenhouse limits) should be used for current RV surveys and Kepler mission to obtain a lower limit on η⊕, so that future flagship missions like TPF-C and Darwin are not undersized. Our model does not include the radiative effects of clouds; thus, the actual HZ boundaries may extend further in both directions than the estimates just given.

Continue Reading →

Debris Disks as Signposts of Terrestrial Planet Formation (A&A, 2012)

We present models for the formation of terrestrial planets, and the collisional evolution of debris disks, in planetary systems that contain multiple marginally unstable gas giants. We previously showed that in such systems, the dynamics of the giant planets introduces a correlation between the presence of terrestrial planets and cold dust, i.e., debris disks, which is particularly pronounced at λ ~ 70 μm. Here we present new simulations that show that this connection is qualitatively robust to a range of parameters: the mass distribution of the giant planets, the width and mass distribution of the outer planetesimal disk, and the presence of gas in the disk when the giant planets become unstable. We discuss how variations in these parameters affect the evolution. We find that systems with equal-mass giant planets undergo the most violent instabilities, and that these destroy both terrestrial planets and the outer planetesimal disks that produce debris disks.

Continue Reading →

Tidal obliquity evolution of potentially habitable planets (Astronomy and Astrophysics, 2011)

We apply two equilibrium tide theories – a constant-phase-lag model and a constant-time-lag model – to compute the obliquity evolution of terrestrial planets orbiting in the habitable zones around LMSs. The time for the obliquity to decrease from an Earth-like obliquity of 23.5° to 5°, the “tilt erosion time”, is compared to the traditional insolation habitable zone (IHZ) in the parameter space spanned by the semi-major axis a, the eccentricity e, and the stellar mass Ms. We also compute tidal heating and equilibrium rotation caused by obliquity tides as further constraints on habitability. The Super-Earth Gl581 d and the planet candidate Gl581 g are studied as examples for these tidal processes.

Continue Reading →

Nitrogen-enhanced greenhouse warming on early Earth (Nature Geoscience, 2009)

Here we use a radiative–convective climate model to show that more N2 in the atmosphere would have increased the warming effect of existing greenhouse gases by broadening their absorption lines. With the atmospheric CO2 and CH4 levels estimated for 2.5 billion years ago, a doubling of the present atmospheric nitrogen (PAN) level would cause a warming of 4.4 ∘C. Our new budget of Earth’s geological nitrogen reservoirs indicates that there is a sufficient quantity of nitrogen in the crust (0.5 PAN) and mantle (>1.4 PAN) to have supported this, and that this nitrogen was previously in the atmosphere. In the mantle, N correlates with 40Ar, the daughter product of 40K, indicating that the source of mantle N is subducted crustal rocks in which NH4+ has been substituted for K+. We thus conclude that a higher nitrogen level probably helped warm the early Earth, and suggest that the effects of N2 should be considered in assessing the habitable zone for terrestrial planets.

Continue Reading →

Building the Terrestrial Planets: Constrained Accretion in the Inner Solar System (Icarus, 2009)

To date, no accretion model has succeeded in reproducing all observed constraints in the inner Solar System. These constraints include: (1) the orbits, in particular the small eccentricities, and (2) the masses of the terrestrial planets – Mars’ relatively small mass in particular has not been adequately reproduced in previous simulations; (3) the formation timescales of Earth and Mars, as interpreted from Hf/W isotopes; (4) the bulk structure of the asteroid belt, in particular the lack of an imprint of planetary embryo-sized objects; and (5) Earth’s relatively large water content, assuming that it was delivered in the form of water-rich primitive asteroidal material. Here we present results of 40 high-resolution (N = 1000–2000) dynamical simulations of late-stage planetary accretion with the goal of reproducing these constraints, although neglecting the planet Mercury.

Continue Reading →

Spectral signatures of photosynthesis. I. Review of Earth organisms (Astrobiology, 2007)

Why do plants reflect in the green and have a “red edge” in the red, and should extrasolar photosynthesis be the same? We provide (1) a brief review of how photosynthesis works, (2) an overview of the diversity of photosynthetic organisms, their light harvesting systems, and environmental ranges, (3) a synthesis of photosynthetic surface spectral signatures, and (4) evolutionary rationales for photosynthetic surface reflectance spectra with regard to utilization of photon energy and the planetary light environment. We found the “near-infrared (NIR) end” of the red edge to trend from blue-shifted to reddest for (in order) snow algae, temperate algae, lichens, mosses, aquatic plants, and finally terrestrial vascular plants. The red edge is weak or sloping in lichens. Purple bacteria exhibit possibly a sloping edge in the NIR. More studies are needed on pigment–protein complexes, membrane composition, and measurements of bacteria before firm conclusions can be drawn about the role of the NIR reflectance. Pigment absorbance features are strongly correlated with features of atmospheric spectral transmittance: P680 in Photosystem II with the peak surface incident photon flux density at ∼685 nm, just before an oxygen band at 687.5 nm; the NIR end of the red edge with water absorbance bands and the oxygen A-band at 761 nm; and bacteriochlorophyll reaction center wavelengths with local maxima in atmospheric and water transmittance spectra. Given the surface incident photon flux density spectrum and resonance transfer in light harvesting, we propose some rules with regard to where photosynthetic pigments will peak in absorbance: (1) the wavelength of peak incident photon flux; (2) the longest available wavelength for core antenna or reaction center pigments; and (3) the shortest wavelengths within an atmospheric window for accessory pigments. That plants absorb less green light may not be an inefficient legacy of evolutionary history, but may actually satisfy the above criteria.

Continue Reading →

Spectral signatures of photosynthesis. II. Coevolution with other stars and the atmosphere on extrasolar worlds (Astrobiology, 2007)

As photosynthesis on Earth produces the primary signatures of life that can be detected astronomically at the global scale, a strong focus of the search for extrasolar life will be photosynthesis, particularly photosynthesis that has evolved with a different parent star. We take previously simulated planetary atmospheric compositions for Earth-like planets around observed F2V and K2V, modeled M1V and M5V stars, and around the active M4.5V star AD Leo; our scenarios use Earth’s atmospheric composition as well as very low O2 content in case anoxygenic photosynthesis dominates. With a line-by-line radiative transfer model, we calculate the incident spectral photon flux densities at the surface of the planet and under water. We identify bands of available photosynthetically relevant radiation and find that photosynthetic pigments on planets around F2V stars may peak in absorbance in the blue, K2V in the red-orange, and M stars in the near-infrared, in bands at 0.93–1.1 μm, 1.1–1.4 μm, 1.5–1.8 μ m, and 1.8–2.5 μm.

Continue Reading →