Venus As A Laboratory For Exoplanetary Science (Journal of Geophysical Research: Planets, 2019)

The current goals of the astrobiology community are focused on developing a framework for the detection of biosignatures, or evidence thereof, on objects inside and outside of our solar system. A fundamental aspect of understanding the limits of habitable environments (surface liquid water) and detectable signatures thereof is the study of where the boundaries of such environments can occur. Such studies provide the basis for understanding how a once inhabitable planet might come to be uninhabitable

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The Nitrogen Budget of Earth (Earth-Science Reviews, 2015)

We comprehensively compile and review N content in geologic materials to calculate a new N budget for Earth. Using analyses of rocks and minerals in conjunction with N–Ar geochemistry demonstrates that the Bulk Silicate Earth (BSE) contains ~ 7 ± 4 times present atmospheric N (4 × 1018 kg N, or PAN), with 27 ± 16 × 1018 kg N. Comparison to chondritic composition, after subtracting N sequestered into the core, yields a consistent result, with BSE N between 17 ± 13 × 1018 kg to 31 ± 24 × 1018 kg N. Embedded in the chondritic comparison we calculate a N mass in Earth’s core (180 ± 110 to 30 ± 180 × 1018 kg) as well as present discussion of the Moon as a proxy for the early mantle.

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Diminished greenhouse warming from Archean methane due to solar absorption lines (Climate of the Past, 2015)

High methane concentrations are thought to have helped sustain warm surface temperatures on the early Earth (~3 billion years ago) when the sun was only 80% as luminous as today. However, radiative transfer calculations with updated spectral data show that methane is a stronger absorber of solar radiation than previously thought. In this paper we show that the increased solar absorption causes a redcution in the warming ability of methane in the Archaean atmosphere.

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Using raindrops to constrain past atmospheric density (Earth and Planetary Science Letters, 2015)

We propose several changes to the method, the most important of which is increasing the maximum possible drop size from to be consistent with new large datasets of raindrop observations. With these changes, our upper bound on modern surface density becomes , a valid limit. The upper bound on Archean atmospheric density is then revised to . In general, we find that raindrop imprint size distribution depends much more strongly on rainfall rate than atmospheric density, which translates into large errors. At best, the precision of raindrop palaeopycnometry will be a factor of a few to an order of magnitude.

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Low Simulated Radiation Limit for Runaway Greenhouse Climates (Nature Geoscience, 2013)

The atmospheres of terrestrial planets are expected to be in long-term radiation balance: an increase in the absorption of solar radiation warms the surface and troposphere, which leads to a matching increase in the emission of thermal radiation. Warming a wet planet such as Earth would make the atmosphere moist and optically thick such that only thermal radiation emitted from the upper troposphere can escape to space. Hence, for a hot moist atmosphere, there is an upper limit on the thermal emission that is unrelated to surface temperature. If the solar radiation absorbed exceeds this limit, the planet will heat uncontrollably and the entire ocean will evaporate—the so-called runaway greenhouse. Here we model the solar and thermal radiative transfer in incipient and complete runaway greenhouse atmospheres at line-by-line spectral resolution using a modern spectral database. We find a thermal radiation limit of 282 W m−2 (lower than previously reported) and that 294 W m−2 of solar radiation is absorbed (higher than previously reported). Therefore, a steam atmosphere induced by such a runaway greenhouse may be a stable state for a planet receiving a similar amount of solar radiation as Earth today. Avoiding a runaway greenhouse on Earth requires that the atmosphere is subsaturated with water, and that the albedo effect of clouds exceeds their greenhouse effect. A runaway greenhouse could in theory be triggered by increased greenhouse forcing, but anthropogenic emissions are probably insufficient.

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Tidal Venuses: Triggering a Climate Catastrophe via Tidal Heating (AAS Meeting Abstracts, 2013)

Traditionally, stellar radiation has been the only heat source considered capable of determining global climate on long timescales. Here, we show that terrestrial exoplanets orbiting low-mass stars may be tidally heated at high-enough levels to induce a runaway greenhouse for a long-enough duration for all the hydrogen to escape. Without hydrogen, the planet no longer has water and cannot support life. We call these planets “Tidal Venuses” and the phenomenon a “tidal greenhouse.” Tidal effects also circularize the orbit, which decreases tidal heating. Hence, some planets may form with large eccentricity, with its accompanying large tidal heating, and lose their water, but eventually settle into nearly circular orbits (i.e., with negligible tidal heating) in the habitable zone (HZ).

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Tidal Venuses: Triggering a Climate Catastrophe via Tidal Heating (Astrobiology, 2013)

Traditionally, stellar radiation has been the only heat source considered capable of determining global climate on long timescales. Here, we show that terrestrial exoplanets orbiting low-mass stars may be tidally heated at high-enough levels to induce a runaway greenhouse for a long-enough duration for all the hydrogen to escape. Without hydrogen, the planet no longer has water and cannot support life. We call these planets “Tidal Venuses” and the phenomenon a “tidal greenhouse.” Tidal effects also circularize the orbit, which decreases tidal heating. Hence, some planets may form with large eccentricity, with its accompanying large tidal heating, and lose their water, but eventually settle into nearly circular orbits (i.e., with negligible tidal heating) in the habitable zone (HZ).

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Timing of Neoproterozoic glaciations linked to transport-limited global weathering (Nature Geoscience, 2011)

Here we show that when this transport-determined limitation is incorporated into the COPSE biogeochemical model6, the stabilization time is substantially longer, >107 years. When we include a simple ice-albedo feedback, the model produces greenhouse–icehouse oscillations on this timescale that are compatible with observations. Our simulations also indicate positive carbon isotope excursions and an increased flux of oxygen to the atmosphere during interglacials, both of which are consistent with the geological record7,8. We conclude that the long gaps between snowball glaciations can be explained by limitations on silicate weathering rates.

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Faint Young Sun Paradox Remains (Nature, 2011)

The Sun was fainter when the Earth was young, but the climate was generally at least as warm as today; this is known as the ‘faint young Sun paradox’. Rosing et al.1 claim that the paradox can be resolved by making the early Earth’s clouds and surface less reflective. We show that, even with the strongest plausible assumptions, reducing cloud and surface albedos falls short by a factor of two of resolving the paradox. A temperate Archean climate cannot be reconciled with the low level of CO2 suggested by Rosing et al.1; a stronger greenhouse effect is needed.

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Clouds and the Faint Young Sun Paradox (Climate of the Past, 2011)

We investigate the role which clouds could play in resolving the Faint Young Sun Paradox (FYSP). Lower solar luminosity in the past means that less energy was absorbed on Earth (a forcing of −50 W m−2 during the late Archean), but geological evidence points to the Earth having been at least as warm as it is today, with only very occasional glaciations. We perform radiative calculations on a single global mean atmospheric column. We select a nominal set of three layered, randomly overlapping clouds, which are both consistent with observed cloud climatologies and reproduced the observed global mean energy budget of Earth.

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Nitrogen-enhanced greenhouse warming on early Earth (Nature Geoscience, 2009)

Here we use a radiative–convective climate model to show that more N2 in the atmosphere would have increased the warming effect of existing greenhouse gases by broadening their absorption lines. With the atmospheric CO2 and CH4 levels estimated for 2.5 billion years ago, a doubling of the present atmospheric nitrogen (PAN) level would cause a warming of 4.4 ∘C. Our new budget of Earth’s geological nitrogen reservoirs indicates that there is a sufficient quantity of nitrogen in the crust (0.5 PAN) and mantle (>1.4 PAN) to have supported this, and that this nitrogen was previously in the atmosphere. In the mantle, N correlates with 40Ar, the daughter product of 40K, indicating that the source of mantle N is subducted crustal rocks in which NH4+ has been substituted for K+. We thus conclude that a higher nitrogen level probably helped warm the early Earth, and suggest that the effects of N2 should be considered in assessing the habitable zone for terrestrial planets.

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