Earth as a Proxy Exoplanet: Deconstructing and Reconstructing Spectrophotometric Light Curves (The Astronomical Journal, 2021)

Point-source spectrophotometric (single-point) light curves of Earth-like planets contain a surprising amount of information about the spatial features of those worlds. Spatially resolving these light curves is important for assessing time-varying surface features and the existence of an atmosphere, which in turn is critical to life on Earth and significant for determining habitability on exoplanets. Given that Earth is the only celestial body confirmed to harbor life, treating it as a proxy exoplanet by analyzing time-resolved spectral images provides a benchmark in the search for habitable exoplanets. The Earth Polychromatic Imaging Camera (EPIC) on the Deep Space Climate Observatory (DSCOVR) provides such an opportunity, with observations of ~5000 full-disk sunlit Earth images each year at 10 wavelengths with high temporal frequency. We disk-integrate these spectral images to create single-point light curves and decompose them into principal components (PCs). Using machine-learning techniques to relate the PCs to six preselected spatial features, we find that the first and fourth PCs of the single-point light curves, contributing ~83.23% of the light-curve variability, contain information about low and high clouds, respectively. Surface information relevant to the contrast between land and ocean reflectance is contained in the second PC, while individual land subtypes are not easily distinguishable (<0.1% total light-curve variation). We build an Earth model by systematically altering the spatial features to derive causal relationships to the PCs. This model can serve as a baseline for analyzing Earth-like exoplanets and guide wavelength selection and sampling strategies for future observations.

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A Statistical Estimation of the Occurrence of Extraterrestrial Intelligence in the Milky Way Galaxy (Galaxies, 2021)

In the field of astrobiology, the precise location, prevalence, and age of potential extraterrestrial intelligence (ETI) have not been explicitly explored. Here, we address these inquiries using an empirical galactic simulation model to analyze the spatial–temporal variations and the prevalence of potential ETI within the Galaxy. This model estimates the occurrence of ETI, providing guidance on where to look for intelligent life in the Search for ETI (SETI) with a set of criteria, including well-established astrophysical properties of the Milky Way. Further, typically overlooked factors such as the process of abiogenesis, different evolutionary timescales, and potential self-annihilation are incorporated to explore the growth propensity of ETI. We examine three major parameters: (1) the likelihood rate of abiogenesis (?A); (2) evolutionary timescales (Tevo); and (3) probability of self-annihilation of complex life (Pann). We found Pann to be the most influential parameter determining the quantity and age of galactic intelligent life. Our model simulation also identified a peak location for ETI at an annular region approximately 4 kpc from the galactic center around 8 billion years (Gyrs), with complex life decreasing temporally and spatially from the peak point, asserting a high likelihood of intelligent life in the galactic inner disk. The simulated age distributions also suggest that most of the intelligent life in our galaxy are young, thus making observation or detection difficult. View Full-Text

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Sulfur Monoxide Dimer Chemistry as a Possible Source of Polysulfur in the Upper Atmosphere of Venus (Nature Communications, 2021)

The abundance of SO dimers (SO)2 in the upper atmosphere of Venus and their implications for the enigmatic ultraviolet absorption has been investigated in several studies over the past few years. However, the photochemistry of sulfur species in the upper atmosphere of Venus is still not well understood and the identity of the missing ultraviolet absorber(s) remains unknown. Here we update an existing photochemical model of Venus’ upper atmosphere by including the photochemistry of SO dimers. Although the spectral absorption profile of SO dimers fits the unknown absorber, their abundance is found to be too low for them to contribute significantly to the absorption. It is more likely that their photolysis and/or reaction products could contribute more substantively. Reactions of SO dimers are found to be important sources of S2O, and possibly higher order SnO species and polysulfur, Sn. All of these species absorb in the critical ultraviolet region and are expected to be found in both the aerosol and gas phase. indicating that in-situ high resolution aerosol mass spectrometry might be a useful technique for identifying the ultraviolet absorber on Venus.

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Quantifying Mineral-Ligand Structural Similarities: Bridging the Geological World of Minerals with the Biological World of Enzymes (Life, 2020)

Metal compounds abundant on Early Earth are thought to play an important role in the origins of life. Certain iron-sulfur minerals for example, are proposed to have served as primitive metalloenzyme cofactors due to their ability to catalyze organic synthesis processes and facilitate electron transfer reactions. An inherent difficulty with studying the catalytic potential of many metal compounds is the wide range of data and parameters to consider when searching for individual minerals and ligands of interest. Detecting mineral-ligand pairs that are structurally analogous enables more relevant selections of data to study, since structural affinity is a key indicator of comparable catalytic function. However, current structure-oriented approaches tend to be subjective and localized, and do not quantify observations or compare them with other potential targets. Here, we present a mathematical approach that compares structural similarities between various minerals and ligands using molecular similarity metrics. We use an iterative substructure search in the crystal lattice, paired with benchmark structural similarity methods. This structural comparison may be considered as a first stage in a more advanced analysis tool that will include a range of chemical and physical factors when computing mineral-ligand similarity. This approach will seek relationships between the mineral and enzyme worlds, with applications to the origins of life, ecology, catalysis, and astrobiology.

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Surface Mapping of Earth-like Exoplanets using Single Point Light Curves (Journal of Visualized Experiments, 2020)

Spatially resolving exoplanet features from single-point observations is essential for evaluating the potential habitability of exoplanets. The ultimate goal of this protocol is to determine whether these planetary worlds harbor geological features and/or climate systems. We present a method of extracting information from multi-wavelength single-point light curves and retrieving surface maps. It uses singular value decomposition (SVD) to separate sources that contribute to light curve variations and infer the existence of partially cloudy climate systems. Through analysis of the time series obtained from SVD, physical attributions of principal components (PCs) could be inferred without assumptions of any spectral properties. Combining with viewing geometry, it is feasible to reconstruct surface maps if one of the PCs are found to contain surface information. Degeneracy originated from convolution of the pixel geometry and spectrum information determines the quality of reconstructed surface maps, which requires the introduction of regularization. For the purpose of demonstrating the protocol, multi-wavelength light curves of Earth, which serves as a proxy exoplanet, are analyzed. Comparison between the results and the ground truth is presented to show the performance and limitation of the protocol. This work provides a benchmark for future generalization of exoplanet applications

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Methane release on Early Mars by atmospheric collapse and atmospheric reinflation (Planetary and Space Science, 2020)

A candidate explanation for Early Mars rivers is atmospheric warming due to surface release of H2 or CH4 gas. However, it remains unknown how much gas could be released in a single event. We model the CH4 release by one mechanism for rapid release of CH4 from clathrate. By modeling how CH4-clathrate release is affected by changes in Mars’ obliquity and atmospheric composition, we find that a large fraction of total outgassing from CH4 clathrate occurs following Mars’ first prolonged atmospheric collapse. This atmosphere-collapse-initiated CH4-release mechanism has three stages. (1) Rapid collapse of Early Mars’ carbon dioxide atmosphere initiates a slower shift of water ice from high ground to the poles. (2) Upon subsequent CO2-atmosphere re-inflation and CO2-greenhouse warming, low-latitude clathrate decomposes and releases methane gas. (3) Methane can then perturb atmospheric chemistry and surface temperature, until photochemical processes destroy the methane.

Within our model, we find that under some circumstances a Titan-like haze layer would be expected to form, consistent with transient deposition of abundant complex abiotic organic matter on the Early Mars surface. We also find that this CH4-release mechanism can warm Early Mars, but special circumstances are required in order to uncork 1017 ?kg of CH4, the minimum needed for strong warming. Specifically, strong warming only occurs when the fraction of the hydrate stability zone that is initially occupied by clathrate exceeds 10%, and when Mars’ first prolonged atmospheric collapse occurs for atmospheric pressure >1 ?bar.

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Searching for Planets Orbiting ? Cen A with the James Webb Space Telescope (PASP, 2019)

? Centauri A is the closest solar-type star to the Sun and offers an excellent opportunity to detect the thermal emission of a mature planet heated by its host star. The MIRI coronagraph on the James Webb Space Telescope can search the 1–3 au (1”–2”) region around ? Cen A which is predicted to be stable within the ? Cen AB system. We demonstrate that with reasonable performance of the telescope and instrument, a 20 hr program combining on-target and reference star observations at 15.5 ?m could detect thermal emission from planets as small as ~5 R?. Multiple visits every 3–6 months would increase the geometrical completeness, provide astrometric confirmation of detected sources, and push the radius limit down to ~3 R?. An exozodiacal cloud only a few times brighter than our own should also be detectable, although a sufficiently bright cloud might obscure any planet present in the system. While current precision radial velocity (PRV) observations set a limit of 50–100 M? at 1–3 au for planets orbiting ? Cen A, there is a broad range of exoplanet radii up to 10 R? consistent with these mass limits. A carefully planned observing sequence along with state-of-the-art post-processing analysis could reject the light from ? Cen A at the level of ~10?5 at 1”–2” and minimize the influence of ? Cen B located 7”–8” away in the 2022–2023 timeframe. These space-based observations would complement on-going imaging experiments at shorter wavelengths as well as PRV and astrometric experiments to detect planets dynamically. Planetary demographics suggest that the likelihood of directly imaging a planet whose mass and orbit are consistent with present PRV limits is small, ~5%, and possibly lower if the presence of a binary companion further reduces occurrence rates. However, at a distance of just 1.34 pc, ? Cen A is our closest sibling star and certainly merits close scrutiny.

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Diurnal variation in Mars equatorial odd oxygen species: Chemical production and loss mechanisms (Icarus, 2020)

Odd oxygen (O, O(1D), O3) abundance and its variability in the Martian atmosphere results from complex physical and chemical interactions among atmospheric species, which are driven mainly by solar radiation and atmospheric conditions. Although our knowledge of Mars’ ozone distribution and variability has been significantly improved with the arrival of several recent orbiters, the data acquired by such missions is not enough to properly characterize its diurnal variation. Thus, photochemical models are useful tools to assist in such a characterization. Here, both the Martian ozone vertical distribution and its diurnal variation for equatorial latitudes are studied, using the JPL/Caltech one-dimensional photochemical model and diurnally-variable atmospheric profiles. The chosen equatorial latitude-region is based on the recent and future plans of NASA and other agencies to study this region by different surface missions. A production and loss analysis is performed in order to characterize the chemical mechanisms that drive odd oxygen’s diurnal budget and variability on Mars making use of the comprehensive chemistry implemented in the model. The diurnal variation shows large differences in the abundance between daytime and nighttime; and variable behavior depending on the atmospheric layer. The photolysis-driven ozone diurnal profile is obtained at the surface, whilst a sharp decrease is obtained in the upper troposphere at daytime, which originates from the large differences in atomic oxygen abundances between atmospheric layers. Finally, no clear anticorrelation between ozone and water vapor is found in the diurnal cycle, contrary to the strong correlation observed by orbiters on a seasonal timescale.

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A Ground-Based Albedo Upper Limit for HD 189733b From Polarimetry (the Astrophysical Journal, 2015)

We present 50 nights of polarimetric observations of HD 189733 in the B band using the POLISH2 aperture-integrated polarimeter at the Lick Observatory Shane 3-m telescope. This instrument, commissioned in 2011, is designed to search for Rayleigh scattering from short-period exoplanets due to the polarized nature of scattered light. Since these planets are spatially unresolvable from their host stars, the relative contribution of the planet-to-total system polarization is expected to vary with an amplitude of the order of 10 parts per million (ppm) over the course of the orbit.

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Bimodal Distribution of Sulfuric Acid Aerosols in the Upper Haze of Venus (Icarus, 2013)

Observations by the SPICAV/SOIR instruments aboard Venus Express have revealed that the upper haze (UH) of Venus, between 70 and 90 km, is variable on the order of days and that it is populated by two particle modes. We use a one-dimensional microphysics and vertical transport model based on the Community Aerosol and Radiation Model for Atmospheres to evaluate whether interaction of upwelled cloud particles and sulfuric acid particles nucleated in situ on meteoric dust are able to generate the two observed modes, and whether their observed variability are due in part to the action of vertical transient winds at the cloud tops. Nucleation of photochemically produced sulfuric acid onto polysulfur condensation nuclei generates mode 1 cloud droplets, which then diffuse upwards into the UH. Droplets generated in the UH from nucleation of sulfuric acid onto meteoric dust coagulate with the upwelled cloud particles and therefore cannot reproduce the observed bimodal size distribution. By comparison, the mass transport enabled by transient winds at the cloud tops, possibly caused by sustained subsolar cloud top convection, are able to generate a bimodal size distribution in a time scale consistent with Venus Express observations.

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A Systematic Retrieval Analysis of Secondary Eclipse Spectra. I. A Comparison of Atmospheric Retrieval Techniques (the Astrophysical Journal, 2013)

Exoplanet atmosphere spectroscopy enables us to improve our understanding of exoplanets just as remote sensing in our own solar system has increased our understanding of the solar system bodies. The challenge is to quantitatively determine the range of temperatures and molecular abundances allowed by the data, which is often difficult given the low information content of most exoplanet spectra that commonly leads to degeneracies in the interpretation. A variety of spectral retrieval approaches have been applied to exoplanet spectra, but no previous investigations have sought to compare these approaches. We compare three different retrieval methods: optimal estimation, differential evolution

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